Highly ordered mesoporous silica film nanocomposites containing gold nanoparticles for the catalytic reduction of 4-nitrophenol

• Mohamad Azani Jalani,
• Leny Yuliati,
• Siew Ling Lee and
• Hendrik O. Lintang

Beilstein J. Nanotechnol. 2019, 10, 1368–1379, doi:10.3762/bjnano.10.135

• . Such catalytic activity is due to the presence of gold nanoparticles of smaller size in the silicate channels of the highly ordered mesoporous film nanocomposites. Keywords: catalyst; gold nanoparticle; mesoporous silica; nanocomposite; thermal hydrogen reduction; 4-nitrophenol reduction

Performance of natural-dye-sensitized solar cells by ZnO nanorod and nanowall enhanced photoelectrodes

• Saif Saadaoui,
• Mohamed Aziz Ben Youssef,
• Moufida Ben Karoui,
• Rached Gharbi,
• Emanuele Smecca,
• Vincenzina Strano,
• Salvo Mirabella,
• Alessandra Alberti and
• Rosaria A. Puglisi

Beilstein J. Nanotechnol. 2017, 8, 287–295, doi:10.3762/bjnano.8.31

• represents the photoelectrode, composed of a wide band gap semiconductor thin layer coated on transparent conducting oxide (TCO) films. A mesoporous film layer is used as a semiconductor in the photoelectrode. Because of its stability and easy synthesis, titanium dioxide (TiO2) is mostly used as the

Cantilever bending based on humidity-actuated mesoporous silica/silicon bilayers

• Christian Ganser,
• Gerhard Fritz-Popovski,
• Roland Morak,
• Parvin Sharifi,
• Benedetta Marmiroli,
• Barbara Sartori,
• Heinz Amenitsch,
• Thomas Griesser,
• Christian Teichert and
• Oskar Paris

Beilstein J. Nanotechnol. 2016, 7, 637–644, doi:10.3762/bjnano.7.56

• bending; grazing incidence small-angle X-ray scattering (GISAXS); mesoporous film; sorption-induced deformation; Introduction Because the bending of a microcantilever can be measured with extremely high accuracy, sensors utilizing this principle are in focus of recent research. Such sensors are able, for

• most likely induced by the sorption-induced deformation of the mesoporous film. Therefore, we attribute the strong change in the slope of the curves seen in Figure 2 (about 70% RH for adsorption and about 55% RH for desorption) to the transition from film formation on the pore walls to the spontaneous

• data shown in Figure 2 reflect the cantilever deflection due to the change in humidity with an accuracy better than 5%. Characterization of mesoporous films A mesoporous film on silicon substrate was prepared in the same way as the film on AFM cantilever to obtain a macroscopically extended film for

Mesoporous MgTa₂O₆ thin films with enhanced photocatalytic activity: On the interplay between crystallinity and mesostructure

• Jin-Ming Wu,
• Igor Djerdj,
• Till von Graberg and
• Bernd M. Smarsly

Beilstein J. Nanotechnol. 2012, 3, 123–133, doi:10.3762/bjnano.3.13

• temperature-dependent X-ray scattering. Optimal activity was obtained when the mesoporous film was heated to 790 °C; at this temperature, crystallinity was significantly high, with MgTa2O6 nanocrystals of 1.6 nm in size (averaged over all reflections), and an ordered mesoporous structure was maintained. When

• of MgTa2O6 in the KLE-templated mesoporous film increased with increasing calcination temperature from 760 up to 1100 °C. The average grain size, which was estimated by applying the Rietveld refinement, is shown in Figure 2 as a function of the calcination temperature for both mesoporous and

• measure of crystal anisotropy. It is obvious that the nonporous crystallites appear with a larger anisotropy (larger grains in [103] direction) compared to their mesoporous counterparts. When the calcination temperature was increased from 760 to 1100 °C the grain size of MgTa2O6 in the mesoporous film